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Highly Selective Synthesis of Enamines from Olefins

✍ Scribed by Moballigh Ahmed; Abdul Majeed Seayad; Ralf Jackstell; Matthias Beller

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
141 KB
Volume
42
Category
Article
ISSN
0044-8249

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## Abstract The reaction of 10‐azidoacetyl‐10__H__‐phenothiazine with olefinic dipolarophiles depends on the reaction temperature. In refluxing toluene, a mixture of enamine and aziridine is formed in 3:1 ratio. The reaction mechanism appears to involve a Michael‐type addition of the nucleophilic _