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Amines Made Easily: A Highly Selective Hydroaminomethylation of Olefins.

✍ Scribed by Moballigh Ahmed; Abdul Majeed Seayad; Ralf Jackstell; Matthias Beller


Publisher
John Wiley and Sons
Year
2003
Weight
176 KB
Volume
34
Category
Article
ISSN
0931-7597

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Highly Regioselective Hydroaminomethylat
✍ Guodu Liu; Kexuan Huang; Chaoxian Cai; Bonan Cao; Mingxin Chang; Prof. Wenjun Wu πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 208 KB

## Abstract A highly regioselective hydroaminomethylation of terminal olefins catalyzed by Rh complexes with 2, 2β€², 6, 6′‐tetrakis ((diphenylphosphino)methyl)‐1, 1′‐biphenyl (Tetrabi) ligand has been developed. Up to 99 % amine selectivity, 168 linear/branched amine product ratio (__n/i__), and 97.