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Highly selective hydrogenation of CC double bond in unsaturated carbonyl compounds over NiC catalyst

✍ Scribed by Nagendranath Mahata; Adelino F. Cunha; José J.M. Órfão; José L. Figueiredo


Book ID
113526572
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
399 KB
Volume
188
Category
Article
ISSN
1385-8947

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Selective CC bond hydrogenation in unsa
✍ Ibrahim Amer; Tamar Bravdo; Jochanan Blum; K. Peter; C. Vollhardt 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 124 KB

The ion pair formed from aqueous rhodium trichloride and Aliquat 336 catalyzes the selective hydrogenation of olefinic C-C bonds of a variety of unsaturated nitro compounds in a two liquid phase system at 30°C. Nitrobenzene gives, under these conditions, a mixture of aniline and nitrocyclohexane.