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Highly Selective Cobalt-Catalyzed Hydrovinylation of Styrene

✍ Scribed by Michiel M. P. Grutters; Jarl Ivar van der Vlugt; Yuxin Pei; Allison M. Mills; Martin Lutz; Anthony L. Spek; Christian Müller; Christina Moberg; Dieter Vogt


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
328 KB
Volume
351
Category
Article
ISSN
1615-4150

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An Efficient Cobalt(I) Catalyst System f
✍ Gerhard Hilt; François-Xavier du Mesnil; Steffen Lüers 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 154 KB 👁 2 views

Not a Diels-Alder reaction but a 1,4-hydrovinylation takes place on treatment of 1,3-dienes with functionalized alkenes in the presence of the catalyst system [CoBr (dppe)]/ZnI /Bu NBH (dppe = 1,2-bis(diphenylphosphanyl)ethane). With this reaction the 1,4-dienes with different substituents R -R can