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Highly rigid and stable porous Cu(i) metal–organic framework with reversible single-crystal-to-single-crystal structural transformation

✍ Scribed by Mohapatra, Sudip; Sato, Hiroshi; Matsuda, Ryotaro; Kitagawa, Susumu; Maji, Tapas Kumar

Book ID: 111866449
Publisher: Royal Society of Chemistry
Year: 2012
Tongue: English
Weight: 637 KB
Volume: 14
Category: Article
ISSN: 1466-8033
DOI: 10.1039/c2ce06701c

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## Abstract A 3D porous metal‐organic framework [Zn~3~(ntb)~2~(EtOH)~2~]~__n__~⋅4__n__EtOH (1) that generates 1D channels of honeycomb aperture has been prepared by the solvothermal reaction of Zn(NO~3~)~2~⋅6 H~2~O and 4,4′,4′′‐nitrilotrisbenzoic acid (H~3~NTB) in EtOH at 110 °C. Framework 1 exhibi