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Reversible Breaking and Forming of Metal–Ligand Coordination Bonds: Temperature-Triggered Single-Crystal to Single-Crystal Transformation in a Metal–Organic Framework

✍ Scribed by María C. Bernini; Felipe Gándara; Marta Iglesias; Natalia Snejko; Enrique Gutiérrez-Puebla; Elena V. Brusau; Griselda E. Narda; M. Ángeles Monge

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
546 KB
Volume
15
Category
Article
ISSN
0947-6539

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Reversible Transformation of ZnII Coordi
Reversible Transformation of ZnII Coordination Geometry in a Single Crystal of Porous Metal-Organic Framework [Zn3(ntb)2(EtOH)2]⋅4 EtOH
✍ Myunghyun Paik Suh; Young Eun Cheon; Eun Young Lee 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 861 KB

## Abstract A 3D porous metal‐organic framework [Zn~3~(ntb)~2~(EtOH)~2~]~__n__~⋅4__n__EtOH (1) that generates 1D channels of honeycomb aperture has been prepared by the solvothermal reaction of Zn(NO~3~)~2~⋅6 H~2~O and 4,4′,4′′‐nitrilotrisbenzoic acid (H~3~NTB) in EtOH at 110 °C. Framework 1 exhibi