Highly resolved photoelectron spectra of the HCl inner valence shell
β Scribed by M.Y. Adam
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 525 KB
- Volume
- 128
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Highly resolved photoelectron spectra have been obtained using synchrotron radiation in the 30 to 90 eV photon energy range; they show the limit of the "complete" breakdown of the molecular-orbital picture when ionization takes place from the inner valence shell of HCL Evidence of a minimum in the corresponding partial cross section suggests that interchannel coupling has to be included in order to describe the complete valence shell photoionization process.
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Inner-shell photoabsorption and valence-level'photoelectron spectra of gaseous SFe, SF&I, and SeFe have been obtained using synchrotron radiation spanning a 21.2-215 eV energy range. The resulting total photoabsorption cross sections of sulphur 2p (LII III) in SFe, sulphur and chlorine 2p (LII III)
hlulttplc scattcrmg Xa calculatrons of the elrctrontc structure of several Ianth.mide iluortdss are performed. It is shoan that thu model IS useful for a quahtatw undcrstandmg ot the features oi tnner shell photoclcctron spectra of these compounds. \* As a referee kindly pointed out, Werthctm et ai.