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Highly regio- and stereospecific hydroxylation of C-1 position of 2-deacetoxytaxinine J derivative with DMDO

✍ Scribed by Tohru Horiguchi; Qian Cheng; Takayuki Oritani


Book ID
108379755
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
119 KB
Volume
41
Category
Article
ISSN
0040-4039

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## Abstract The ^1^H NMR parameters of the NCH~2~O protons in the spectrum of perhydropyrrolo[1,2‐__c__][1,3]oxazine show its existence in solution at room temperature in the __O__‐inside __cis__‐fused conformation. __rel__‐(3a__S__,6a__S__,6b__R__,10a__S__,11a__S__)‐6a‐Methylperhydroindolo[3,2,1‐_