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Highly Regio- and Stereoselective Synthesis of 2(E),4-Alkadienoates via the Pd(0)-Catalyzed Reaction of Aryl Halides with 3,4-Alkadienoates.

โœ Scribed by Chunling Fu; Shengming Ma


Publisher
John Wiley and Sons
Year
2005
Weight
24 KB
Volume
36
Category
Article
ISSN
0931-7597

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โœ Xiaoyi Chen; Wei Kong; Haiting Cai; Lichun Kong; Gangguo Zhu ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons โš– 31 KB

## Abstract The palladiumโ€catalyzed haloallylation of alkynes (I) in dichloromethane leads stereoselectively to (E)โ€dihalodienes (III), whereas (Z)โ€isomers (IV) are readily obtained by the same reaction in acetic acid in the presence of lithium halides.