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Highly Functionalized Organolithium and Organoboron Reagents for the Preparation of Enantiomerically Pure α-Amino Acids.

✍ Scribed by Christopher W. Barfoot; Joanne E. Harvey; Martin N. Kenworthy; John Paul Kilburn; Mahmood Ahmed; Richard J. K. Taylor

Publisher
John Wiley and Sons
Year
2005
Weight
34 KB
Volume
36
Category
Article
ISSN
0931-7597

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Enantiomerically Pure Highly Functionalized α-Amino Ketones from the Reaction of Chiral Cyclic N-(9-Phenylfluoren-9-yl) α-Amido Esters with Organolithium Reagents. -Treatment of the cyclic αand β-amino esters (II), (V), and (VIII) with organolithium compounds is found to give the corresponding keto