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Highly Enantioselective Synthesis of β-Heteroaryl-Substituted Dihydrochalcones Through Friedel–Crafts Alkylation of Indoles and Pyrrole

✍ Scribed by Wentao Wang; Xiaohua Liu; Weidi Cao; Jun Wang; Lili Lin; Xiaoming Feng

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 295 KB
Volume: 16
Category: Article
ISSN: 0947-6539
DOI: 10.1002/chem.200902355

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## Abstract magnified image The Lewis base‐Lewis base bifunctional catalytic system has been developed and successfully applied to the asymmetric Friedel–Crafts alkylation of indoles with α,β‐unsaturated aldehydes. The reactions are promoted by chiral diphenylprolinol trimethylsilyl ether in the p