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Highly Enantioselective Ring Opening of Epoxides Catalyzed by (salen)Cr(III) Complexes

✍ Scribed by Martinez, Luis E.; Leighton, James L.; Carsten, Douglas H.; Jacobsen, Eric N.

Book ID: 111864209
Publisher: American Chemical Society
Year: 1995
Tongue: English
Weight: 280 KB
Volume: 117
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00126a048

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a Unless otherwise noted, the reaction condition: cyclohexene oxide (1 mmol), PhSH (1.2 mmol), catalyst (10 mol %). b Isolated yields. c Determined by HPLC with a Daicel Chiralcel OD column. Absolute configurations of the major enantiomers (1S,2S) were assigned by comparison of the rotation values