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Highly Enantioselective Hydrogenation of α-Keto Esters Catalyzed by Ru-Tunephos Complexes.

✍ Scribed by Chun-Jiang Wang; Xianfeng Sun; Xumu Zhang

Publisher
John Wiley and Sons
Year
2006
Weight
21 KB
Volume
37
Category
Article
ISSN
0931-7597

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Enantioselective Hydrogenation of β-Keto Esters Catalyzed by P-Chiral Bis(dialkylphosphino)ethanes-Ru(II). -The asymmetric hydrogenation of β-keto esters or related compounds to the corresponding secondary alcohols is readily achieved with a homogeneous Ru-catalyst based on a P-chiral bis(dialkylph