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Highly Enantioselective Diels−Alder Reactions of Danishefsky Type Dienes with Electron-Deficient Alkenes Catalyzed by Yb(III)-BINAMIDE Complexes

✍ Scribed by Sudo, Yukinori; Shirasaki, Daisuke; Harada, Shinji; Nishida, Atsushi


Book ID
127277824
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
100 KB
Volume
130
Category
Article
ISSN
0002-7863

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Highly enantioselective Diels–Alder reac
✍ Shinji Harada; Nozomi Toudou; Shiharu Hiraoka; Atsushi Nishida 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 389 KB

The synthesis and utility of the novel axially chiral bis-urea ligand BINUREA are described. A complex of this urea ligand with ytterbium triflate and DBU can be used in the catalytic enantioselective Diels-Alder reaction of Danishefsky-type diene and electron-deficient olefins to give the adducts i