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Enantioselective Aza-Diels−Alder Reaction of Aldimines with “Danishefsky-Type Diene” Catalyzed by Chiral Scandium(III)- N , N ‘ -Dioxide Complexes

✍ Scribed by Shang, Deju; Xin, Junguo; Liu, Yanling; Zhou, Xin; Liu, Xiaohua; Feng, Xiaoming


Book ID
126989888
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
155 KB
Volume
73
Category
Article
ISSN
0022-3263

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✍ Shinji Harada; Nozomi Toudou; Shiharu Hiraoka; Atsushi Nishida 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 389 KB

The synthesis and utility of the novel axially chiral bis-urea ligand BINUREA are described. A complex of this urea ligand with ytterbium triflate and DBU can be used in the catalytic enantioselective Diels-Alder reaction of Danishefsky-type diene and electron-deficient olefins to give the adducts i