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Highly Enantioselective Cyanosilylation of Aldehydes Catalyzed by Novel β-Amino Alcohol−Titanium Complexes

✍ Scribed by Li, Yan; He, Bin; Qin, Bo; Feng, Xiaoming; Zhang, Guolin

Book ID
120189095
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
95 KB
Volume
69
Category
Article
ISSN
0022-3263

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✍ Zhaoqing Xu; Rui Wang; Jiangke Xu; Chao-shan Da; Wen-jin Yan; Chao Chen 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 89 KB 👁 2 views

The enantioselective formation of C À C bonds is an area of intense research. [1,2] The asymmetric addition of alkynyl reagents to aldehydes is very useful for the synthesis of chiral secondary propargyl alcohols, which are important building blocks for many chiral organic compounds. [3] Several stu