Highly Enantioselective Conjugate Addition of Diethylzinc to Acyclic Enones with Fine-Tunable Phosphite−Pyridine Ligands
✍ Scribed by Wan, Huihui; Hu, Yuanchun; Liang, Yuxue; Gao, Shuang; Wang, Junwei; Zheng, Zhuo; Hu, Xinquan
- Book ID
- 125989903
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 69 KB
- Volume
- 68
- Category
- Article
- ISSN
- 0022-3263
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Four phosphites obtained by linking enantiomerically pure binaphthylchlorophosphite to the two different hydroxy groups of deoxycholic acid were synthesized and used as chiral ligands in the enantioselective copper-catalyzed 1,4-addition of diethylzinc to acyclic enones. The ligands were screened fo