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Highly Enantioselective Conjugate Addition of AlMe3 to Linear Aliphatic Enones by a Designed Catalyst.

✍ Scribed by Paul K. Fraser; Simon Woodward

Publisher
John Wiley and Sons
Year
2003
Weight
24 KB
Volume
34
Category
Article
ISSN
0931-7597

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Highly Enantioselective Conjugate Additi
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✍ Paul K. Fraser; Simon Woodward πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 162 KB πŸ‘ 2 views

## Abstract 2‐Hydroxy‐2′‐alkylthio‐1,1′‐binaphthyl compounds are catalytic promoters of the 1,4‐addition of AlMe~3~ to linear aliphatic enones in THF at βˆ’40 to βˆ’48 °C in the presence of [Cu(MeCN)~4~]BF~4~. At ligand loadings of 5–20 mol %, enantioselectivities of 80–93 % are realised for most subst

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v