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Highly Enantioselective Catalytic Thiolysis of Prochiral Cyclic Dicarboxylic Anhydrides Utilizing a Bifunctional Chiral Sulfonamide.

โœ Scribed by Takashi Honjo; Shigeki Sano; Motoo Shiro; Yoshimitsu Nagao


Publisher
John Wiley and Sons
Year
2006
Weight
33 KB
Volume
37
Category
Article
ISSN
0931-7597

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Highly Enantioselective Catalytic Thioly
โœ Takashi Honjo; Shigeki Sano; Motoo Shiro; Yoshimitsu Nagao ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 123 KB

Asymmetric differentiation between two identical carbonyl groups of prochiral s-symmetric dicarboxylic acid derivatives by using an enzymatic or a nonenzymatic procedure is a rational and useful strategy for the asymmetric synthesis of biologically active compounds and medicines. The resultant chira