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Highly Enantioselective Catalytic 1,3-Dipolar Cycloaddition Involving 2,3-Allenoate Dipolarophiles

✍ Scribed by Yu, Jie; He, Long; Chen, Xiao-Hua; Song, Jin; Chen, Wei-Jie; Gong, Liu-Zhu

Book ID
120278622
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
216 KB
Volume
11
Category
Article
ISSN
1523-7060

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Cycloaddition mechanisms can be separated phenomenologically into three classes. (1) concerted, (2) stepwise--diradical intermediate, and (3) stepwise--zwitterionic intermediate.