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Kinetic Resolution of Racemic 2,3-Allenoates by Organocatalytic Asymmetric 1,3-Dipolar Cycloaddition

✍ Scribed by Yu, Jie; Chen, Wei-Jie; Gong, Liu-Zhu

Book ID
120278613
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
482 KB
Volume
12
Category
Article
ISSN
1523-7060

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Chiral non racemic carbazate 1, derived from (R)-(-)-phenylglycinol, reacts regioselectively with benzaldehyde or its dimethylacetal to give an azomethine imine. The faci~d, endo/exo and regio selectivities of 1,3-dipolar cycloadditions of this reactive species with various dipolarophiles have been