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Highly enantioselective arylation of ketones

✍ Scribed by Oscar Prieto; Diego J Ramón; Miguel Yus

Book ID
104359863
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
88 KB
Volume
14
Category
Article
ISSN
0957-4166

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✦ Synopsis

The enantioselective arylation of different ketones was successfully performed using several arylzinc reagents, titanium tetraisopropoxide and substoichiometric amounts of trans-1,2-bis(hydroxycamphorsulfonylamino)cyclohexane as chiral C 2 -symmetric ligand, the enantiomeric excess reaching up to 96%.

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