✦ LIBER ✦

Highly efficient total synthesis of manoalide and seco-manoalide via Pd(0) catalyzed coupling of allyhalide with CO and 2-silyl-4-stannylfuran

✍ Scribed by Shigeo Katsumura; Shinya Fujiwara; Sachihiko Isoe

Book ID: 104220185
Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 242 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)86680-0

No coin nor oath required. For personal study only.

✦ Synopsis

Total synthesis of manoalide and seco-manoalide from an allylchlolide derivative was achieved by 6 steps in 56.4% overall yield by Pd(0) catalyzed coupling with CO and 2-trimethylsilyl-4-tributylstannylfuran followed by chemoselective oxidation of 2-trimethylsilylfuran with '02.

📜 SIMILAR VOLUMES

ChemInform Abstract: Efficient Synthesis

ChemInform Abstract: Efficient Synthesis of 2,3-Dihydrofurans via the Highly Selective Pd(0)-Catalyzed Coupling-Cyclization Reaction of 3,4-Allenols with Aryl Iodides.

✍ Shengming Ma; Wenzhong Gao 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

Highly Regio- and Stereoselective Synthe

Highly Regio- and Stereoselective Synthesis of 2(E),4-Alkadienoates via the Pd(0)-Catalyzed Reaction of Aryl Halides with 3,4-Alkadienoates.

✍ Chunling Fu; Shengming Ma 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 24 KB 👁 1 views

Highly Regio- and Stereoselective Synthe

Highly Regio- and Stereoselective Synthesis of Polysubstituted Cyclopropane Compounds via the Pd(0)-Catalyzed Coupling—Cyclization Reaction of 2-(2′,3′-Allenyl)malonates with Organic Halides.

✍ Shengming Ma; Ning Jiao; Qing Yang; Zilong Zheng 📂 Article 📅 2005 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

## Abstract For Abstract see ChemInform Abstract in Full Text.

Highly Regio- and Stereoselective Synthe

Highly Regio- and Stereoselective Synthesis of Polysubstituted Cyclopropane Compounds via the Pd(0)-Catalyzed Coupling−Cyclization Reaction of 2-(2‘,3‘-Allenyl)malonates with Organic Halides

✍ Ma, Shengming; Jiao, Ning; Yang, Qing; Zheng, Zilong 📂 Article 📅 2004 🏛 American Chemical Society 🌐 English ⚖ 95 KB

ChemInform Abstract: Efficient Synthesis

ChemInform Abstract: Efficient Synthesis of 2,3-Dihydro-1H-pyrazoles via a Highly Selective Pd(0)-Catalyzed Coupling—Cyclization Reaction of Terminal 2-Substituted 2,3-Allenyl Hydrazines with Aryl Iodides.

✍ Xin Cheng; Shengming Ma 📂 Article 📅 2009 🏛 John Wiley and Sons ⚖ 37 KB 👁 3 views

Efficient Synthesis of 4-(2‘-Alkenyl)-2,

Efficient Synthesis of 4-(2‘-Alkenyl)-2,5-dihydrofurans and 5,6-Dihydro-2 H -pyrans via the Pd-Catalyzed Cyclizative Coupling Reaction of 2,3- or 3,4-Allenols with Allylic Halides

✍ Ma, Shengming; Gao, Wenzhong 📂 Article 📅 2002 🏛 American Chemical Society 🌐 English ⚖ 214 KB