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Highly efficient synthesis of homoallylic alcohols and amines via allylation of aldehydes and imines catalyzed by ZrOCl2·8H2O in water

✍ Scribed by Wei Shen; Li-Min Wang; Jian-Jun Feng; He Tian

Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
103 KB
Volume
49
Category
Article
ISSN
0040-4039

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✦ Synopsis

The allylation of aldehydes and imines has efficiently been carried out by treatment with allyltributylstannane in the presence of a catalytic amount of ZrOCl 2 Á8H 2 O in water to form the corresponding homoallylic alcohols and amines, respectively, in high yields.

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Efficient one-pot synthesis of functionalized piperidine scaffolds via ZrOCl2·8H2O catalyzed tandem reactions of aromatic aldehydes with amines and acetoacetic esters
✍ Sarita Mishra; Rina Ghosh 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 595 KB

A highly efficient diastereoselective one-pot synthesis of functionalized piperidines has been developed based on an aqua-compatible ZrOCl 2 Á8H 2 O catalyst via tandem reactions of aromatic aldehydes, amines, and acetoacetic esters.