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Highly efficient Kharasch addition catalysed by RuCl(Cp*)(PPh3)2

✍ Scribed by François Simal; Lise Wlodarczak; Albert Demonceau; Alfred F Noels

Book ID
108379906
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
144 KB
Volume
41
Category
Article
ISSN
0040-4039

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Atom-Transfer Radical Addition (ATRA) an
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## Abstract A new catalytic procedure for atom‐transfer radical addition (ATRA) and cyclization (ATRC) reactions is described. The combination of the ruthenium(III) complex [RuCl~2~Cp\*(PPh~3~)] (Cp\*: pentamethylcyclopentadienyl) with magnesium allows these reactions to be performed under mild con