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Highly efficient asymmetric epoxidation of alkenes with a novel chiral complex of ruthenium(III) containing a sugar based ligand and triphenylphosphines

โœ Scribed by Debabrata Chatterjee; Susan Basak; Abdelkhalek Riahi; Jacques Muzart

Book ID
108212712
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
253 KB
Volume
255
Category
Article
ISSN
1381-1169

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Asymmetric epoxidation of alkenes with a
Asymmetric epoxidation of alkenes with aqueous t-BuOOH catalyzed by novel chiral complexes of chromium(III) containing tridentate Schiff-base ligands
โœ Debabrata Chatterjee; Susan Basak; Jacques Muzart ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 361 KB

The [Cr III (ฮฑ-TDL 1 \*)(bipy)(Cl)] ( 1) and [Cr III (TDL 2 \*)(bipy)(Cl)] ( 2) complexes (where H 2 TDL 1 \* = N-3,5-di-(t-butyl)salicylidine-dglucosamine, H 2 TDL 2 \* = N-3,5-di-(tertiarybutyl)salicylidine-l-alanine, bipy = bipyridyl) have been synthesized and characterized by analytical, spectra