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Highly Diastereoselective Synthesis of Chimeras of Proline and Glutamate.

✍ Scribed by Konstantin V. Kudryavtsev; Mikhail Yu. Tsentalovich; Anton S. Yegorov; Eugene L. Kolychev

Publisher
John Wiley and Sons
Year
2007
Weight
23 KB
Volume
38
Category
Article
ISSN
0931-7597

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Highly diastereoselactive synthesis of chimeras of proline and glutamate
✍ Konstantin V. Kudryavtsev; Mikhail Yu. Tsentalovich; Anton S. Yegorov; Eugene L. πŸ“‚ Article πŸ“… 2006 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 448 KB

## Abstract magnified image Azomethine ylides have been generated from aromatic aldimines of α‐amino acid methyl esters under treatment with LiBr/Et~3~N and trapped with __tert__‐butyl acrylate yielding racemic orthogonally protected __cis__‐5‐arylpyrrolidine‐2,4‐dicarboxylates regio‐ and stereo‐s