𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Highly Diastereoselective Oxy-Michael Additions of Enantiopure δ-Lactol Anions to Nitroalkenes: Asymmetric Synthesis of 1,2-Amino Alcohols.

✍ Scribed by Nicola J. Adderley; David J. Buchanan; Darren J. Dixon; Dramane I. Laine

Publisher
John Wiley and Sons
Year
2003
Weight
155 KB
Volume
34
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Diastereoselective 1,2-Addition of Organ
Diastereoselective 1,2-Addition of Organometallic Reagents to Chiral Formylferrocenes Leading to Enantiomerically Pure Ferrocenyl Amino Alcohols: Application to Asymmetric Dialkylzinc Addition to Aldehydes and Synthesis of Optically Active 1,2-Homodisubstituted Ferrocenes
✍ Shin-ichi Fukuzawa; Daisuke Tsuchiya; Kae Sasamoto; Kohki Hirano; Makoto Ohtaguc 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 341 KB 👁 2 views

The chiral formylferrocenes 2-5 have been readily prepared in good yields by ortho-lithiation of the TMS-blocked orunblocked aminoferrocenes and subsequent reaction with DMF. The stereochemistry of the reaction of 2 with organometallic reagents has been examined. Reactions of 2 with Grignard and org