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Highly diastereoselective electrophilic additions to the vinylcyclopropane moiety of a homotropylidene system

โœ Scribed by Mauro Freccero; Anna Gamba; Remo Gandolfi; Mirko Sarzi Amade'


Book ID
108374652
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
901 KB
Volume
53
Category
Article
ISSN
0040-4020

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ChemInform Abstract: Highly Diastereosel
โœ M. FRECCERO; A. GAMBA; R. GANDOLFI; M. S. AMADE ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 34 KB ๐Ÿ‘ 1 views

Highly Diastereoselective Electrophilic Additions to the Vinylcyclopropane Moiety of a Homotropylidene System. -A study of the diastereoselective TosOH catalyzed addition of AcOH and MeOH to the tetracycle (I) is presented. ฮฒ-Derivatives, e.g. (III) and (V), are highly prevalent over their ฮฑ-counte