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Highly diastereoselective addition of organometallics to novel chiral α-ketoamides of (S)-2-methoxymethylindoline

✍ Scribed by Yong Hae Kim; Il Suk Byun; Jun Young Choi

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
133 KB
Volume
6
Category
Article
ISSN
0957-4166

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Diastereoselective addition of organomet
Diastereoselective addition of organometallic reagents to chiral iminium ions: Synthesis of (S)-(+)-cryptostyline I.
✍ Richard P. Polniaszek; Lawrence W. Dillard 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 271 KB

lminium ion 2c participates in stereoselective nucleophilic addition reactions wkh Grfgnard reagents. Analysis of the products from reaction of 5hexenylmagnesium bromide with iminium ion 2a suggests that these reactions proceed by a polar (two electron) mechanism. The utility of this chemistry is de