ChemInform Abstract: Highly Diastereosel
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N. MASE; Y. WATANABE; Y. UENO; T. TORU
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Article
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2010
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John Wiley and Sons
⚖ 43 KB
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Highly Diastereoselective Intermolecular β-Addition of Alkyl Radicals to Chiral 2-(Arylsulfinyl)-2-cycloalkenones. -The reaction of cycloalkenones having chiral bulky arylsulfinyl groups proceeds with excellent diastereoselectivity. In the presence of the Lewis acids EtAlCl 2 and TiCl 2 (OiPr) 2 re