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Highly Chlorinated, Brominated, and Iodinated Icosahedral Carborane Anions: 1-H-CB 11 X 11- , 1-CH 3 -CB 11 X 11- (X = Cl, Br, I); 1-Br-CB 11 Br 11-

✍ Scribed by Xie, Zuowei; Tsang, Chi-Wing; Sze, Eric Tung-Po; Yang, Qingchuan; Chan, Dominic T. W.; Mak, Thomas C. W.

Book ID: 120308091
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 188 KB
Volume: 37
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic9805628

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## Abstract Selective monoiodination of a series of carba‐__closo__‐dodecaborates with a halogen atom or a hydroxy substituent bonded to the antipodal boron atom resulted in salts of the novel anions [7‐I‐12‐X‐__closo__‐CB~11~H~10~]^–^ [X = F (1), Cl (2), Br (3), OH (4)]. These anions were isolated