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Highly chemoselective reductive amination-coupling by one-pot reaction of aldehydes, HMDS and NaBH4

✍ Scribed by Najmedin Azizi; Elham Akbari; Alireza Khejeh Amiri; Mohammad R. Saidi

Book ID: 104095824
Publisher: Elsevier Science
Year: 2008
Tongue: French
Weight: 166 KB
Volume: 49
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.09.048

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✦ Synopsis

An efficient and highly chemoselective synthesis of symmetrical secondary amines via reductive amination of aldehydes with inexpensive and commercially available HMDS and sodium borohydride in high to quantitative yields is reported.

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