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Highly Asymmetric Michael Addition to α,β-Unsaturated Ketones Catalyzed by 9-Amino-9-deoxyepiquinine.

✍ Scribed by Jian-Wu Xie; Wei Chen; Rui Li; Mi Zeng; Wei Du; Lei Yue; Ying-Chun Chen; Yong Wu; Jin Zhu; Jin-Gen Deng

Publisher
John Wiley and Sons
Year
2007
Weight
43 KB
Volume
38
Category
Article
ISSN
0931-7597

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Highly Asymmetric Michael Addition to α,
Highly Asymmetric Michael Addition to α,β-Unsaturated Ketones Catalyzed by 9-Amino-9-deoxyepiquinine
✍ Jian-Wu Xie; Wei Chen; Rui Li; Mi Zeng; Wei Du; Lei Yue; Ying-Chun Chen; Yong Wu 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 130 KB

## Dedicated to Prof. Yao-Zhong Jiang on the occasion of his 70th birthday The in situ generation of an iminium ion from a chiral aminocatalyst and a carbonyl compound is thought to lower the LUMO energy of the system and is a powerful strategy for a range of asymmetric transformations. [1] The co