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ChemInform Abstract: Highly Enantioselective Conjugate Addition of 1-Bromonitroalkanes to α,β-Unsaturated Ketones Catalyzed by 9-Amino-9-deoxyepiquinine.

✍ Scribed by Li-ting Dong; Rui-jiong Lu; Quan-sheng Du; Jun-min Zhang; Sheng-ping Liu; Yi-ning Xuan; Ming Yan

Publisher
John Wiley and Sons
Year
2009
Weight
33 KB
Volume
40
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES

Highly Asymmetric Michael Addition to α,
Highly Asymmetric Michael Addition to α,β-Unsaturated Ketones Catalyzed by 9-Amino-9-deoxyepiquinine
✍ Jian-Wu Xie; Wei Chen; Rui Li; Mi Zeng; Wei Du; Lei Yue; Ying-Chun Chen; Yong Wu 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 130 KB

## Dedicated to Prof. Yao-Zhong Jiang on the occasion of his 70th birthday The in situ generation of an iminium ion from a chiral aminocatalyst and a carbonyl compound is thought to lower the LUMO energy of the system and is a powerful strategy for a range of asymmetric transformations. [1] The co