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Higher-order effects in the EPR spectrum of the monodeutero-tert-butyl radical

โœ Scribed by P Burkhard; H Fischer


Publisher
Elsevier Science
Year
1980
Weight
654 KB
Volume
40
Category
Article
ISSN
0022-2364

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Rate constants for the reaction of tert-
โœ H.-R. Dรผtsch; H. Fischer ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 699 KB

## Abstract The decay of photochemically generated __tert__โ€butyl radicals in methylcyclopentane solutions containing chloroform is studied by timeโ€resolved ESR spectroscopy. In the pure solvent it perfectly follows the secondโ€order rate law for radical selfโ€termination. Increasing chloroform conce