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High Temperature Shock Tube and Theoretical Studies on the Thermal Decomposition of Dimethyl Carbonate and Its Bimolecular Reactions with H and D-Atoms

✍ Scribed by Peukert, S. L.; Sivaramakrishnan, R.; Michael, J. V.


Book ID
127379356
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
947 KB
Volume
117
Category
Article
ISSN
1089-5639

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Shock-tube studies on the reactions of d
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## Abstract The reactions of dimethyl ether (CH~3~OCH~3~, DME) with O(^3^P) and H atoms have been studied at high temperatures by using a shock tube apparatus coupled with atomic resonance absorption spectroscopy (ARAS). The rate coefficients for the reactions CH~3~OCH~3~ + O(^3^P) β†’ CH~3~OCH~2~ +