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High Temperature End of the So-Called “Koga Line”: Anomalies in Temperature Derivatives of Heat Capacities

✍ Scribed by Koga, Yoshikata; Westh, Peter; Moriya, Yosuke; Kawasaki, Koji; Atake, Tooru

Book ID
120927516
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
134 KB
Volume
113
Category
Article
ISSN
0022-3654

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✍ Peter Westh; Aase Hvidt; Yoshikata Koga 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 353 KB

Weak jump anomalies were observed in the temperature derivatives of the heat capacities of aqueous 2-butoxyethanol. The derivative, (flC,/aT), is proportional to the third derivative of the Gibbs free energy with respect to T. The loci of these anomalies in the composition-temperature field fall on