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Anomalies in the Third Derivatives of Gibbs Energy and Their Temperature Dependence in Aqueous 2-Butoxyethanol and Glycerol: On the so Called Koga Lines

โœ Scribed by Yoshida, Koh; Inaba, Akira; Koga, Yoshikata


Book ID
121588332
Publisher
Springer US
Year
2013
Tongue
English
Weight
504 KB
Volume
43
Category
Article
ISSN
0095-9782

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โœ Peter Westh; Aase Hvidt; Yoshikata Koga ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 353 KB

Weak jump anomalies were observed in the temperature derivatives of the heat capacities of aqueous 2-butoxyethanol. The derivative, (flC,/aT), is proportional to the third derivative of the Gibbs free energy with respect to T. The loci of these anomalies in the composition-temperature field fall on