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High-Spin Organocobalt(II) Complexes in a Thioether Coordination Environment

✍ Scribed by DuPont, Julie A.; Coxey, Michael B.; Schebler, Peter J.; Incarvito, Christopher D.; Dougherty, William G.; Yap, Glenn P. A.; Rheingold, Arnold L.; Riordan, Charles G.

Book ID
126795080
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
168 KB
Volume
26
Category
Article
ISSN
0276-7333

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Magnetic properties of a penta-coordinated high-spin cobalt(II) complex: acetate-N-methyl-octaethylporphyrinato-cobalt(II)
✍ Kouichi Fukui; Hiroaki Ohya-Nishiguchi; Noboru Hirota; Katsuhiro Aoyagi; Hisanob πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 435 KB

It is shown by EPR and magnetic susceptibility (x) measurements that acetate-N-methyl-octaethylporphyrinato-Co(I1) has a high-spin ground state. The complex in toluene gives EPR spectra with g= 4.4 and 2.04 and x with kn= 4.4 BM and Dz 20 cm-', which indicates square-pyramidal geometry around Co( II