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Antiferromagnetic Coupling in a Six-Coordinate High Spin Cobalt(II)−Semiquinonato Complex

✍ Scribed by Caneschi, Andrea; Dei, Andrea; Gatteschi, Dante; Tangoulis, Vassilis

Book ID
121507602
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
63 KB
Volume
41
Category
Article
ISSN
0020-1669

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Magnetic properties of a penta-coordinated high-spin cobalt(II) complex: acetate-N-methyl-octaethylporphyrinato-cobalt(II)
✍ Kouichi Fukui; Hiroaki Ohya-Nishiguchi; Noboru Hirota; Katsuhiro Aoyagi; Hisanob 📂 Article 📅 1987 🏛 Elsevier Science 🌐 English ⚖ 435 KB

It is shown by EPR and magnetic susceptibility (x) measurements that acetate-N-methyl-octaethylporphyrinato-Co(I1) has a high-spin ground state. The complex in toluene gives EPR spectra with g= 4.4 and 2.04 and x with kn= 4.4 BM and Dz 20 cm-', which indicates square-pyramidal geometry around Co( II