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High-spin .fwdarw. low-spin relaxation kinetics and cooperative effects in the hexakis(1-propyltetrazole)iron bis(tetrafluoroborate) and [Zn1-xFex(ptz)6](BF4)2(ptz = 1-propyltetrazole) spin-crossover systems

✍ Scribed by Hauser, Andreas; Guetlich, Philipp; Spiering, Hartmut


Book ID
126869736
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
467 KB
Volume
25
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES


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At low temperatures an external pressure of 1 kbar accelerates the high-spin ~ low-spin relaxation in the [Znl\_xFex(ptz)6](BF4) 2, x = 0.1, spin-crossover system by one order of magnitude. This is due to the large difference in 0 3 volume between the high-spin and low-spin states of 26 A/molecule.

Reversibility of light-induced excited s
✍ A. Hauser πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 438 KB

Fe(ptz)6(BF4)2 (ptz = I-propyltetrazole) is an iron(H) spin-crossover system which shows light-Induced excited spin state trapping. In this paper we show that (a) the same phenomenon can also be observed in Zn, \_ rFeX(ptz)6(BF4)2 (x = 0.1) and is therefore basically a single-ion property, and (b) t