A crossed beam esperiment usmg n surFace ionization negative ion :;ource and a xenon arc lamp has allowed the relative cross seciion tiu photodetachment of an electron from a negative ion of tetracyanoelhylene to be determined for photons in the energy rang 2.1--3.5 cV (590-350 nm). Tha threshold en
High resolution threshold photodetachment spectroscopy of negative ions
β Scribed by T.N. Kitsopoulos; I.M. Waller; J.G. Loeser; D.M. Neumark
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 585 KB
- Volume
- 159
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
We have designed and constructed a negative ion threshold photodetachment spectrometer with 3 cm-' (0.37 meV) resolution. Threshold photodetachment spectra of I-and SH-have been obtained. For SH-. individual rotational transitions between the ion and neutral appear as clearly resolved peaks.
' NSERC (Canada) Postdoctoral Fellow.
π SIMILAR VOLUMES
Rovibrational spectra of Hz, HN:, and H30+ generated in discharge jet-expansion have been studied using a differencefrequency infrared source, The rotational temperatures were determined to be 120 i 20,273 + 20 and 150 -f: 20 K for H: , HN$ , and HsO+, respectively. Some dynamic phenomena of the jet