𝔖 Bobbio Scriptorium
✦   LIBER   ✦

High-Resolution Study of the Three Lowest Infrared Bands of PHD2

✍ Scribed by O.N. Ulenikov; E.S. Bekhtereva; O.L. Petrunina; H. Bürger; W. Jerzembeck

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
211 KB
Volume
214
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

The high-resolution (2.3 × 10 -3 cm -1 ) Fourier transform infrared spectrum of PHD 2 was recorded for the first time and analyzed in the region of the three lowest bands belonging to the three bending fundamentals. Between 1100 and 1800 transitions were assigned to each of the ν 3 , ν 4 , and ν 6 bands and 1267 upper energies were obtained thereof. These were fitted by 58 parameters, which reproduce the experimental upper energies with rms deviations of 1.3×10 -4 cm -1 and 2.7×10 -4 cm -1 for the J ≤ 17 and J ≥ 18 levels, respectively.

📜 SIMILAR VOLUMES

High-Resolution Infrared Study of PHD2:
High-Resolution Infrared Study of PHD2: The P–H Stretching Bands ν1 and 2ν1
✍ O.N Ulenikov; O.L Petrunina; E.S Bekhtereva; E.A Sinitsin; H Bürger; W Jerzembec 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 105 KB

For the first time the infrared spectrum of PHD 2 was recorded in the region of the PH stretching fundamental ν 1 at 2324.005 cm -1 and the overtone 2ν 1 at 4563.634 cm -1 with a resolution of 4.2 × 10 -3 cm -1 and 8.8 × 10 -3 cm -1 , respectively. In the analyses about 1340 and 1020 transitions wer

High-Resolution Infrared Study of the Fu
High-Resolution Infrared Study of the Fundamental Bands of Monoiodoacetylene
✍ A.M. Tolonen; S. Alanko; M. Koivusaari; R. Paso; V.M. Horneman 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 326 KB

The infrared spectrum of monoiodoacetylene has been recorded in certain selected wavenumber regions between 200 and \(3500 \mathrm{~cm}^{-1}\) with a Fourier transform spectrometer at resolutions varying from 0.0025 to \(0.0046 \mathrm{~cm}^{-1}\). All five fundamental bands of the \(\mathrm{HCCI}\)

High-Resolution Infrared Study of the Fu
High-Resolution Infrared Study of the Fundamental Bands of Deuteroiodoacetylene
✍ H. Sarkkinen; A.-M. Tolonen; S. Alanko 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 209 KB

The high-resolution infrared spectrum of deuterated iodoacetylene has been measured in the region 200-2700 cm 01 . In addition to all five fundamentals, the bands 2n 0 4 and 2n 0 5 have been identified. The measurements were carried out by using a Fourier transform spectrometer at room temperature w

High-Resolution Infrared Study of the ν1
High-Resolution Infrared Study of the ν11 Band of Allene
✍ S Nissen; F Hegelund; M.S Johnson; B Nelander 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 115 KB

The high-resolution infrared spectrum of allene has been observed in the 280-380 cm -1 region at a nominal resolution of 0.00125 cm -1 using the IR beamline at the MAX-I electron storage ring in Lund. The spectrum shows the bending fundamental of the ν 11 band from which spectroscopic constants for

High-Resolution Infrared Study of the ν1
High-Resolution Infrared Study of the ν14, ν17, and ν18Bands of11B2H6and10B11BH6
✍ R.L. Sams; T.A. Blake; S.W. Sharpe; J.-M. Flaud; W.J. Lafferty 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 257 KB

Using high-resolution Fourier transform spectra, a thorough analysis of the 14 c-type, 17 a-type, and 18 a-type bands of both 11 B 2 H 6 and 10 B 11 BH 6 has been carried in the 10.3-, 6.2-, and 8.5-m spectral regions, respectively. From this analysis a large set of precise ground state combination

High-Resolution Study of the Mid-Infrare
High-Resolution Study of the Mid-Infrared Region of FNO2
✍ H. Kruse; F. Hegelund; H. Bürger; G. Pawelke 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 255 KB

Of the gas-phase IR spectrum of nitrylfluoride, FNO 2 , between 1200 and 1900 cm Ϫ1 , the bands 4 , 2 6 , 2 ϩ 3 , and 1 have been studied at a resolution of ca. 0.003 cm Ϫ1 . Improved ground state rotational and centrifugal distortion constants have been obtained from a simultaneous analysis of the