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High-resolution study of the infrared band ν2 of CH35Cl3

✍ Scribed by R. Pasa; V.-M. Horneman; J. Pietilä; R. Anttila


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
369 KB
Volume
247
Category
Article
ISSN
0009-2614

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✦ Synopsis


The Fourier transform spectrum of the v 2 band around 676 cm-] of isotopically pure CH35C13 has been measured. The experimental resolution was near 0.0010 cm-t. In this parallel band more than 3000 rotational lines, with Jm~x = 100 and Kma x = 56, were assigned. In the analysis a model for an unperturbed symmetric top band was applied. The fit of 2852 lines, with a standard deviation of 0.17 × l0 -3 cm-l, led, among others, to the following results: v o = 676.643310(9) cm-I, B 2 --B 0 = -0.493903(6) X 10-3 cm-] and C 2 -C o = -0.109899(22) × 10-3 cm-).


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