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High-Resolution Infrared Spectroscopy of the ν2 Band of CH3NC

✍ Scribed by M. Elshakre; C. He; L.P. Gold; R.A. Bernheim

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
240 KB
Volume
161
Category
Article
ISSN
0022-2852

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✦ Synopsis

The first completely resolved vibration-rotation spectrum of the (\nu_{2}) band of (\mathrm{CH}{3} \mathrm{NC}^{2}) was observed and measured between 2100 and (2200 \mathrm{~cm}^{-1}) with an interferometric spectrometer at a spectral resolution of (0.004 \mathrm{~cm}^{-1}). Two hundred sixty-nine resolved transitions were assigned to the (R(J, K)) branches spanning (J=3-57) and (K=3-9). Spectroscopic constants for the (\nu{2}) state of (\mathrm{CH}_{3} \mathrm{NC}) were obtained for the unperturbed portions of the band using a least-squares fit to 236 transitions. 1993 Academic Press, Inc.

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