𝔖 Bobbio Scriptorium
✦   LIBER   ✦

High-resolution laser photofragment spectroscopy of the c 1Π-b 1Σ+ system of OH+

✍ Scribed by David J. Rodgers; Peter J. Sarre

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
405 KB
Volume
143
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The first observation of transitions in the c 'II-b 'E + system of the OH+ molecule has been achieved by fast-ion-beam laser photofragment spectroscopy. The spectrum was recorded by the detection of O+ ions which arise from predissociation of the c 'II state. The assignment of P, Q and R branches of the 3-O band is described and molecular parameters for these two vibrational levels are reported. The rotational constant for u=O agrees well with the value obtained by Merer et al. (Can. J. Phys. 53 (1975) 25 1) from an analysis of perturbations in the A 'II state. Molecular parameters for the c 'II and b 'E + states are in good agreement with those obtained from ab initio calculations of the potential energy curves.

📜 SIMILAR VOLUMES

High-Resolution Laser Spectroscopy of th
High-Resolution Laser Spectroscopy of the A3Π1←X1Σ+ System of IBr with a Titanium:Sapphire Ring Laser
✍ Tokio Yukiya; Nobuo Nishimiya; Masao Suzuki 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 453 KB

The vibrotational absorption spectra of the A ← X electronic transition of I 79/81 Br were measured in the 11 330-to 13 220-cm -1 region using a Ti:sapphire ring laser. The P-, Q-, and R-branch lines of the rotational states from J = 10 to 100 belonging to the v ← v = (3∼20) ← (1∼6) bands were assig

Laser Spectroscopy of the A3Π1 ← X1Σ+ Sy
Laser Spectroscopy of the A3Π1 ← X1Σ+ System of IBr
✍ N. Nishimiya; T. Yukiya; M. Suzuki 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 259 KB

The electronic absorption spectra of the \(A^{3} \Pi_{1} \leftarrow X^{1} \Sigma^{+}\)system of iodine bromides \({ }^{79}{ }^{79} \mathrm{Br}\) and \({ }^{81} \mathrm{Br}\) species were investigated in the region from 11780 to \(12500 \mathrm{~cm}^{-1}\) using a \(\mathrm{GaAs}\) semiconductor lase

High-Resolution Laser Excitation Spectro
High-Resolution Laser Excitation Spectroscopy of the A1Σ+-X1Σ+ Transition of BaS
✍ Z. Morbi; P.F. Bernath 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 610 KB

The high-resolution laser excitation spectrum of the \(A^{1} \Sigma^{+}-X^{1} \Sigma^{+}\)transition of BaS was recorded. The BaS molecule was prepared by a gas-phase reaction of Ba metal vapor with \(\mathrm{CS}_{2}\) in a Broida oven. The \(2-0,3-0,4-0,5-0,5-1,6-1,7-1,7-2,8-2,9-2\), and \(8-3\) vi

High-Resolution Laser Spectroscopy of Yb
High-Resolution Laser Spectroscopy of YbCl: The A2Π–X2Σ+ Transition
✍ Todd C. Melville; John A. Coxon; Colan Linton 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 104 KB

The A 2 ⌸-X 2 ⌺ ϩ transition of 174 Yb 35 Cl and 172 Yb 35 Cl has been rotationally analyzed for the first time. Doppler-limited laser excitation spectroscopy with selective detection of fluorescence was used to obtain spectra of the 0 -0 and 1-0 bands with a measurement accuracy of approximately 0.