The high-resolution FTIR absorption spectra of the NH 2 Cl molecule have been measured in the region 500-3600 cm -1 . The rotational structures of all the fundamental bands and a number of overtone and combination bands have been analyzed. Every rotational line of the observed bands except the NH 2
High resolution FTIR study on NH2Br molecule: amino wagging band
โ Scribed by Ei-ichi Masuko; Yoshiaki Hamada
- Publisher
- Elsevier Science
- Year
- 2003
- Tongue
- English
- Weight
- 171 KB
- Volume
- 222
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
โฆ Synopsis
The amino wagging band of NH 2 Br molecule has been observed in the region from 800 to 1200 cm ร1 with the resolution of 0.006 cm ร1 by a Fourier transform spectrometer. The rotational and centrifugal distortion constants have been determined which reproduce the rotational structures of K 0 a < 6 for both isotopomers of 79 Br and 81 Br. The spectral splittings as much as 0.07 cm ร1 due to the amino inversion motion have been observed and some discussions on the inversion potential have been made.
๐ SIMILAR VOLUMES
The n {1 4 / 2n 0 6 and n |1 4 / 2n {2 6 perpendicular components and the n {1 4 / 2n {2 6 parallel component of the CH 3 79 Br isotopomer have been found and studied in high resolution ( 0.006 cm 01 ) . Both perpendicular components are linked altogether and also to the n 2 / n 3 / n 4 band by anha