𝔖 Bobbio Scriptorium
✦   LIBER   ✦

High Resolution FTIR Study of the First GeH Stretching Overtone Band of H370GeD

✍ Scribed by Hans Bürger; Helmut Ruland; Lauri Halonen

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
274 KB
Volume
182
Category
Article
ISSN
0022-2852

No coin nor oath required. For personal study only.

✦ Synopsis

The IR spectrum of monoisotopic H 3 70 GeD has been recorded in the region of the first GeH stretching overtone near 4200 cm 01 . Three bands have been observed and assigned in the local mode model to (200A 1 ) 4154.139 cm 01 , (200E) 4154.366 cm 01 , and (110E) 4223.07 cm 01 . The low-K sublevels of the (200A 1 /E) states are unperturbed. The analysis of the rotational structure, s(fit) Å 4.3 1 10 04 cm 01 , reveals closeness to local mode behavior although this is less pronounced than for the (300A 1 /E) levels. Perturbations by unknown dark states affect both the (110E) level and the (210E, 1) level at 6265.56 cm 01 that was also analyzed, and Coriolis effects were found to be present here. ᭧ 1997

📜 SIMILAR VOLUMES

Rotational Analysis of thev= 6, 7, and 8
Rotational Analysis of thev= 6, 7, and 8 GeH Stretching Overtone Bands of H370GeD
✍ Hans Bürger; Alain Campargue; Lauri Halonen; Helmut Ruland 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 262 KB

The £( GeH) Å 6, 7, and 8 overtones of monoisotopic H 3 70 GeD have been studied by ICLAS with effective optical path lengths between 9 and 40.8 km at a resolution of ca. 0.05 cm 01 . Rotational structure was resolved and assigned (in the local mode notation) to the (600), 11 649.77 cm 01 , (700), 1

High-Resolution Study of the First Stret
High-Resolution Study of the First Stretching Overtones of H3Si79Br
✍ A. Ceausu; G. Graner; H. Bürger; E.B. Mkadmi; P. Pracna; W.J. Lafferty 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 321 KB

The Fourier transform infrared spectrum of monoisotopic H3Si79Br (resolution 7.7 x 10(-3) cm-1) was studied from 4200 to 4520 cm-1, in the region of the first overtones of the Si-H stretching vibration. The investigation of the spectrum revealed the presence of two band systems, the first consisting

High-Resolution FTIR Spectrum of HSSH in
High-Resolution FTIR Spectrum of HSSH in the SH-Stretching Region: The ν5 Band
✍ P. Mittler; K.M.T. Yamada; G. Winnewisser; M. Birk 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 241 KB

The high-resolution infrared spectrum of the \(v_{5}\) fundamental band (antisymmetric SH stretching) of \(\mathrm{H}_{2} \mathrm{~S}_{2}\) has been measured with a Fourier transform spectrometer. Approximately \(700 \mathrm{H}_{2} \mathrm{~S}_{2}\) transitions of the parallel band were assigned and

High-Resolution Measurements of HBr Tran
High-Resolution Measurements of HBr Transitions in the First Overtone Band Using Tunable Diode Lasers
✍ Shang-I Chou; Douglas S. Baer; Ronald K. Hanson 📂 Article 📅 2000 🏛 Elsevier Science 🌐 English ⚖ 116 KB

High-resolution absorption lineshapes of the R(7) and P(2) transitions in the first overtone (v ϭ 0 -2) band of H 79 Br have been recorded at room temperature using a pair of distributed feedback diode lasers operating near 1.95 and 2.00 m, respectively. Spectral line intensities and self-broadening

High Resolution FTIR Study of the ν5Band
High Resolution FTIR Study of the ν5Bands of HSiD3and H120SnD3
✍ Hans Bürger; Wolfgang Jerzembeck; Helmut Ruland; Lauri Halonen 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 250 KB

High resolution Fourier Transform spectra of HSiD 3 and monoisotopic H 120 SnD 3 have been recorded in the region of the n 5 fundamental at 850.68 and 646.90 cm 01 with a resolution of 3.3 and 2.8 1 10 03 cm 01 , respectively. About 2000 rovibrational transitions of each species have been assigned a