The high-resolution Fourier transform spectrum of the D 2 O molecule were recorded and analyzed in the region near 0.97 µm (10 200-10 440 cm -1 ) where the bands of the v = 4 (v = v 1 + v 2 /2 + v 3 ) polyad are located. Transitions belonging to the strongest band of the polyad, 3ν 1 + ν 3 , are ass
High-Resolution Fourier Transform Spectrum of the D2O Molecule in the Region of the Second Triad of Interacting Vibrational States
✍ Scribed by Sheng-gui He; O.N. Ulenikov; G.A. Onopenko; E.S. Bekhtereva; Xiang-huai Wang; Shui-ming Hu; Hai Lin; Qing-shi Zhu
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 220 KB
- Volume
- 200
- Category
- Article
- ISSN
- 0022-2852
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✦ Synopsis
The high-resolution Fourier transform spectrum of the D 2 O molecule was recorded in the 3200 -4200 cm Ϫ1 region, where the bands of the second triad of interacting vibrational states are located. As a result of the theoretical analysis, both the rotational-vibrational structure of the (011) vibrational state was improved, and the rotational energies of the ( 110) and ( 030) vibrational states were determined for the first time up to rotational quantum numbers J max. ϭ 15 and 14, respectively.
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